此技術為了改善傳統 #哈柏法 的高能耗與碳排放問題,提出以「焦耳加熱法(Joule heating)」快速合成均勻銅基雙金屬 #催化劑(CuNi、CuFe、CuPd),有效提升硝酸鹽(NO₃⁻)在 #電化學反應 中還原為銨離子(NH₄⁺)的效率。該方法能在僅數秒內完成高溫分解與快速冷卻,形成粒徑小、分散均勻的合金奈米催化劑。研究顯示,CuNi 催化劑展現出最佳效能,具有高達 98% 的 銨選擇性 與 49% 的銨產率,遠勝單一金屬 Cu 催化劑。
更重要的是,該方法不僅解決了含硝酸鹽廢水污染問題,還能產出具價值的氨,成功實現「污染源→再生資源」的轉換,為 #循環經濟(Circular Economy)提供一種兼具高效率與永續性的路徑。
DOI: https://doi.org/10.1016/j.seppur.2025.133312
Led
by Prof. Jenn Fang Su of our center, this collaborative research with the
Industrial University of Ho Chi Minh City (#Vietnam) and Universiti Malaysia Pahang (#Malaysia) demonstrates the power of cross-border
scientific collaboration in advancing green energy technologies.
To address the high energy consumption and carbon emissions of the
traditional Haber-Bosch process, the team developed a Joule heating method to
rapidly synthesize homogeneous copper-based bimetallic catalysts (CuNi, CuFe,
CuPd). This ultra-fast method—completed in just seconds—uses high-temperature
decomposition and rapid quenching to form nano-alloy catalysts with uniform
dispersion and small particle sizes.
Among the catalysts, CuNi exhibited the best performance, achieving an ammonium selectivity of 98% and a yield of 49%, outperforming monometallic Cu catalysts significantly in the electrochemical reduction of nitrate (NO₃⁻) to #ammonium (NH₄⁺).
#IndustrialUniversityofHoChiMinhCity #UniversitiMalaysiaPahang #長庚大學 #永續發展與能源科技研究中心 #ChangGungUniversity #JennFangSu #CenterForSustainabilityAndEnergyTechnologies #CGU #CSET #CircularEconomy